Cargando…

Controlled decomposition of SF(6) by electrochemical reduction

The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bouvet, Sébastien, Pégot, Bruce, Sengmany, Stéphane, Le Gall, Erwan, Léonel, Eric, Goncalves, Anne-Marie, Magnier, Emmanuel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2020
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7722628/ https://www.ncbi.nlm.nih.gov/pubmed/33335602 http://dx.doi.org/10.3762/bjoc.16.244

Ejemplares similares

An Electrochemical Synthesis of Functionalized Arylpyrimidines from 4-Amino-6-Chloropyrimidines and Aryl Halides
por: Sengmany, Stéphane, et al.
Publicado: (2011)

Electrochemical and Infrared Absorption Spectroscopy Detection of SF(6) Decomposition Products
por: Dong, Ming, et al.
Publicado: (2017)

Dichlorotrifluoromethoxyacetic Acid: Preparation and Reactivity †
por: Zriba, Riadh, et al.
Publicado: (2017)

Synthesis, Physical Properties and Application of a Series of New Polyoxometalate-Based Ionic Liquids
por: Martinetto, Yohan, et al.
Publicado: (2021)

Chemo- and Diastereoselectivities in the Electrochemical Reduction of Maleimides
por: Rix, Kathryn, et al.
Publicado: (2015)

Thermal Decomposition Properties of Epoxy Resin in SF(6)/N(2) Mixture
por: Wen, Hao, et al.
Publicado: (2018)

Decomposition Characteristics of SF(6) under Flashover Discharge on the Epoxy Resin Surface
por: Wen, Hao, et al.
Publicado: (2019)

Multicomponent SF(6) decomposition product sensing with a gas-sensing microchip
por: Chu, Jifeng, et al.
Publicado: (2021)

General, Practical and Selective Oxidation Protocol for CF(3)S into CF(3)S(O) Group
por: Sokolenko, Liubov V., et al.
Publicado: (2019)

High Sensitivity and Selectivity of AsP Sensor in Detecting SF(6) Decomposition Gases
por: Jin, Wang, et al.
Publicado: (2018)

Application of Excimer Lamp in Quantitative Detection of SF(6) Decomposition Component SO(2)
por: Chen, Tunan, et al.
Publicado: (2021)

Theoretical Study on Adsorption Behavior of SF(6) Decomposition Components on Mg-MOF-74
por: Lei, Tianxiang, et al.
Publicado: (2023)

Effects of SF(6) decomposition components and concentrations on the discharge faults and insulation defects in GIS equipment
por: Zhuang, Yuan, et al.
Publicado: (2020)

Increasing the Affinity of an O‐Antigen Polysaccharide Binding Site in Shigella flexneri Bacteriophage Sf6 Tailspike Protein
por: Kunstmann, Sonja, et al.
Publicado: (2020)

TiO(2) Nanotube Array Sensor for Detecting the SF(6) Decomposition Product SO(2)
por: Zhang, Xiaoxing, et al.
Publicado: (2012)

Direct Electrochemical Addressing of Immobilized Alcohol Dehydrogenase for the Heterogeneous Bioelectrocatalytic Reduction of Butyraldehyde to Butanol
por: Schlager, S, et al.
Publicado: (2015)

Modulating Activity through Defect Engineering of Tin Oxides for Electrochemical CO(2) Reduction
por: Daiyan, Rahman, et al.
Publicado: (2019)

A Pt-Doped TiO(2) Nanotube Arrays Sensor for Detecting SF(6) Decomposition Products
por: Zhang, Xiaoxing, et al.
Publicado: (2013)

A DFT Calculation of Fluoride-Doped TiO(2) Nanotubes for Detecting SF(6) Decomposition Components
por: Zhang, Xiaoxing, et al.
Publicado: (2017)

Ni-CNT Chemical Sensor for SF(6) Decomposition Components Detection: A Combined Experimental and Theoretical Study
por: Gui, Yingang, et al.
Publicado: (2018)

Adsorption Properties of Pd(3)-Modified Double-Vacancy Defect Graphene toward SF(6) Decomposition Products
por: Li, Jie, et al.
Publicado: (2020)

Preparation of mono-substituted malonic acid half oxyesters (SMAHOs)
por: Xavier, Tania, et al.
Publicado: (2021)

Long-term entrapment and temperature-controlled-release of SF(6) gas in metal–organic frameworks (MOFs)
por: Bunzen, Hana, et al.
Publicado: (2019)

Structure and Reactivity of N‐Heterocyclic Alkynyl Hypervalent Iodine Reagents
por: Le Du, Eliott, et al.
Publicado: (2021)

Three‐Phase Electrolysis by Gold Nanoparticle on Hydrophobic Interface for Enhanced Electrochemical Nitrogen Reduction Reaction
por: Zhang, Junchang, et al.
Publicado: (2020)

Enhanced Bio‐Electrochemical Reduction of Carbon Dioxide by Using Neutral Red as a Redox Mediator
por: Seelajaroen, Hathaichanok, et al.
Publicado: (2019)

Dissociative Ionization and Thermal Decomposition of Cyclopentanone
por: Pastoors, Johan I. M., et al.
Publicado: (2017)

Electrochemical Reduction of Carbon Dioxide to Methanol by Direct Injection of Electrons into Immobilized Enzymes on a Modified Electrode
por: Schlager, Stefanie, et al.
Publicado: (2016)

Electrochemical Reduction of O(2) in Ca(2+)‐Containing DMSO: Role of Roughness and Single Crystal Structure
por: Köllisch‐Mirbach, Andreas, et al.
Publicado: (2021)

As-Doped h-BN Monolayer: A High Sensitivity and Short Recovery Time SF(6) Decomposition Gas Sensor
por: Long, Yunfeng, et al.
Publicado: (2022)

Sensitivity Characteristic Analysis of Adsorbent-Mixed Carbon Nanotube Sensors for the Detection of SF(6) Decomposition Products under PD Conditions
por: Zhang, Xiaoxing, et al.
Publicado: (2013)

Analysis of the Sensitivity of K-Type Molecular Sieve-Deposited MWNTs for the Detection of SF(6) Decomposition Gases under Partial Discharge
por: Zhang, Xiaoxing, et al.
Publicado: (2015)

The Adsorption and Sensing Performances of Ir-modified MoS(2) Monolayer toward SF(6) Decomposition Products: A DFT Study
por: Liu, Hongcheng, et al.
Publicado: (2021)

Adsorption of SF(6) Decomposition Products by the S Vacancy Structure and Edge Structure of SnS(2): A Density Functional Theory Study
por: Wang, Jincong, et al.
Publicado: (2021)

First-Principle Study of Rh-Doped Nitrogen Vacancy Boron Nitride Monolayer for Scavenging and Detecting SF(6) Decomposition Products
por: Shi, Zhen, et al.
Publicado: (2021)

A Systems Approach to a One‐Pot Electrochemical Wittig Olefination Avoiding the Use of Chemical Reductant or Sacrificial Electrode
por: Chakraborty, Biswarup, et al.
Publicado: (2020)

From CO(2) to Bioplastic – Coupling the Electrochemical CO(2) Reduction with a Microbial Product Generation by Drop‐in Electrolysis
por: Stöckl, Markus, et al.
Publicado: (2020)

Single Crystal Sub‐Nanometer Sized Cu(6)(SR)(6) Clusters: Structure, Photophysical Properties, and Electrochemical Sensing
por: Gao, Xiaohui, et al.
Publicado: (2016)

Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate
por: Grollier, Kevin, et al.
Publicado: (2020)

Thermal Decomposition of Ternary Sodium Graphite Intercalation Compounds
por: Au, Heather, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_09uchlfh02opheiajaeqme0jgh