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Crystal Structural Investigations for Understanding the Hydrogen Storage Properties of YMgNi(4)-Based Alloys
[Image: see text] The hydrogen storage properties and crystal structures of YMgNi(4)-based alloys, which were synthesized from (2 – x)YNi(2) and xMgNi(2) (0.6 ≤ x ≤ 1.2), were investigated by pressure–composition–temperature measurements and powder neutron diffraction at a deuterium gas pressure to...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7726944/ https://www.ncbi.nlm.nih.gov/pubmed/33324828 http://dx.doi.org/10.1021/acsomega.0c04535 |
Sumario: | [Image: see text] The hydrogen storage properties and crystal structures of YMgNi(4)-based alloys, which were synthesized from (2 – x)YNi(2) and xMgNi(2) (0.6 ≤ x ≤ 1.2), were investigated by pressure–composition–temperature measurements and powder neutron diffraction at a deuterium gas pressure to understand the hydrogen absorption and desorption reactions viewed from atomic arrangements around H atoms. Reducing the amounts of MgNi(2), which was utilized as a Mg source in YMgNi(4)-based alloys, has been observed to lower the hydrogen absorption and desorption pressures and increase the hydrogen storage capacities. However, the reversible hydrogen capacity attained a maximum value of 1.2 mass % at x = 0.8 because of the formation of a thermodynamically stable hydride in which hydrogen was not released at x = 0.6. In the case of x = 0.6, the presence of excessive Y atoms around the H atoms in the hydrogen-absorbed phase would lead to the formation of a hydride with stronger interaction between Y and H because of the affinity between them. Moreover, the presence of small amounts of D atoms with short interatomic D–D distances (1.6 and 1.9 Å) in the deuterium-absorbed phase (Y(0.81)Mg(1.19)Ni(4.00)D(3.35) and Y(1.06)Mg(0.94)Ni(4.00)D(3.86)) at <5 MPa and 323 K was proposed by the crystal structural investigations. The D atoms with short D–D interatomic distances were located in the same local atomic arrangements of D atoms in a deuterium-absorbed phase, which were formed at a higher-pressure range, and had higher hydrogen storage capacities than the deuterium-absorbed phases in this study. |
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