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Facile Fabrication of ZnMgAl/LDH/Algae Composites as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and Equilibrium Studies
[Image: see text] In order to improve the adsorption capacity of natural layered double hydroxyl (LDH) materials, the natural organic sources such as algae containing hydroxyl groups, amino groups, peptide connections, and alginate structures were used to improve LDH for the preparation of ZnMgAl LD...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7727017/ https://www.ncbi.nlm.nih.gov/pubmed/33324845 http://dx.doi.org/10.1021/acsomega.0c04842 |
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author | Said, Ibrahim Abukhadra, Mostafa R. Rabie, Abdelrahman M. Bakr, Al-Sayed A. Shim, Jae-Jin Ahmed, Sayed Abdelkader |
author_facet | Said, Ibrahim Abukhadra, Mostafa R. Rabie, Abdelrahman M. Bakr, Al-Sayed A. Shim, Jae-Jin Ahmed, Sayed Abdelkader |
author_sort | Said, Ibrahim |
collection | PubMed |
description | [Image: see text] In order to improve the adsorption capacity of natural layered double hydroxyl (LDH) materials, the natural organic sources such as algae containing hydroxyl groups, amino groups, peptide connections, and alginate structures were used to improve LDH for the preparation of ZnMgAl LDH-algae composites (LDH-Ax). The structure of prepared composites was established and characterized via various techniques such as scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The LDH-A2 sample displayed the highest efficiency for Cr(VI) removal, which reached to 99% at the optimum conditions. The prepared composite LDH-A2 showed high stability and reusability (91.7%) after five cycles. The kinetic studies revealed that the Cr uptake by LDH-A1 is described as pseudo-first order, while the case of LDH-A2 is described as pseudo-second order. This study reported that the easily synthesized LDH-Ax has an interesting environmental approval process to eliminate Cr ions from aqueous media quickly and effectively. |
format | Online Article Text |
id | pubmed-7727017 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-77270172020-12-14 Facile Fabrication of ZnMgAl/LDH/Algae Composites as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and Equilibrium Studies Said, Ibrahim Abukhadra, Mostafa R. Rabie, Abdelrahman M. Bakr, Al-Sayed A. Shim, Jae-Jin Ahmed, Sayed Abdelkader ACS Omega [Image: see text] In order to improve the adsorption capacity of natural layered double hydroxyl (LDH) materials, the natural organic sources such as algae containing hydroxyl groups, amino groups, peptide connections, and alginate structures were used to improve LDH for the preparation of ZnMgAl LDH-algae composites (LDH-Ax). The structure of prepared composites was established and characterized via various techniques such as scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The LDH-A2 sample displayed the highest efficiency for Cr(VI) removal, which reached to 99% at the optimum conditions. The prepared composite LDH-A2 showed high stability and reusability (91.7%) after five cycles. The kinetic studies revealed that the Cr uptake by LDH-A1 is described as pseudo-first order, while the case of LDH-A2 is described as pseudo-second order. This study reported that the easily synthesized LDH-Ax has an interesting environmental approval process to eliminate Cr ions from aqueous media quickly and effectively. American Chemical Society 2020-11-19 /pmc/articles/PMC7727017/ /pubmed/33324845 http://dx.doi.org/10.1021/acsomega.0c04842 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Said, Ibrahim Abukhadra, Mostafa R. Rabie, Abdelrahman M. Bakr, Al-Sayed A. Shim, Jae-Jin Ahmed, Sayed Abdelkader Facile Fabrication of ZnMgAl/LDH/Algae Composites as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and Equilibrium Studies |
title | Facile Fabrication of ZnMgAl/LDH/Algae Composites
as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and
Equilibrium Studies |
title_full | Facile Fabrication of ZnMgAl/LDH/Algae Composites
as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and
Equilibrium Studies |
title_fullStr | Facile Fabrication of ZnMgAl/LDH/Algae Composites
as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and
Equilibrium Studies |
title_full_unstemmed | Facile Fabrication of ZnMgAl/LDH/Algae Composites
as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and
Equilibrium Studies |
title_short | Facile Fabrication of ZnMgAl/LDH/Algae Composites
as a Potential Adsorbent for Cr(VI) Ions from Water: Fabrication and
Equilibrium Studies |
title_sort | facile fabrication of znmgal/ldh/algae composites
as a potential adsorbent for cr(vi) ions from water: fabrication and
equilibrium studies |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7727017/ https://www.ncbi.nlm.nih.gov/pubmed/33324845 http://dx.doi.org/10.1021/acsomega.0c04842 |
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