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ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials

This paper reports an Alkali-Activated Materials (AAM) using two different precursors, metakaolin and a metallurgical slag with photocatalytic zinc oxide nanoparticles, as novel photocatalytic composites. The photodegradation performance of the composites using methylene blue (MB) dye as a wastewate...

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Autores principales: Guzmán-Carrillo, Hector R., Manzano-Ramírez, Alejandro, Garcia Lodeiro, Ines, Fernández-Jiménez, Ana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7728076/
https://www.ncbi.nlm.nih.gov/pubmed/33255643
http://dx.doi.org/10.3390/molecules25235519
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author Guzmán-Carrillo, Hector R.
Manzano-Ramírez, Alejandro
Garcia Lodeiro, Ines
Fernández-Jiménez, Ana
author_facet Guzmán-Carrillo, Hector R.
Manzano-Ramírez, Alejandro
Garcia Lodeiro, Ines
Fernández-Jiménez, Ana
author_sort Guzmán-Carrillo, Hector R.
collection PubMed
description This paper reports an Alkali-Activated Materials (AAM) using two different precursors, metakaolin and a metallurgical slag with photocatalytic zinc oxide nanoparticles, as novel photocatalytic composites. The photodegradation performance of the composites using methylene blue (MB) dye as a wastewater model was investigated by ultraviolet radiations (UV-vis) spectroscopy. Adsorption in dark conditions and photodegradation under UV irradiation are the mechanisms for removing MB dye. The pseudo-first-order kinetic and pseudo-second-order kinetic models were employed, and the experimental data agreed with the pseudo-second-order model in both cases with UV and without UV irradiations. As new photocatalytic materials, these composites offer an alternative for environmental applications.
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spelling pubmed-77280762020-12-11 ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials Guzmán-Carrillo, Hector R. Manzano-Ramírez, Alejandro Garcia Lodeiro, Ines Fernández-Jiménez, Ana Molecules Article This paper reports an Alkali-Activated Materials (AAM) using two different precursors, metakaolin and a metallurgical slag with photocatalytic zinc oxide nanoparticles, as novel photocatalytic composites. The photodegradation performance of the composites using methylene blue (MB) dye as a wastewater model was investigated by ultraviolet radiations (UV-vis) spectroscopy. Adsorption in dark conditions and photodegradation under UV irradiation are the mechanisms for removing MB dye. The pseudo-first-order kinetic and pseudo-second-order kinetic models were employed, and the experimental data agreed with the pseudo-second-order model in both cases with UV and without UV irradiations. As new photocatalytic materials, these composites offer an alternative for environmental applications. MDPI 2020-11-25 /pmc/articles/PMC7728076/ /pubmed/33255643 http://dx.doi.org/10.3390/molecules25235519 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Guzmán-Carrillo, Hector R.
Manzano-Ramírez, Alejandro
Garcia Lodeiro, Ines
Fernández-Jiménez, Ana
ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title_full ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title_fullStr ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title_full_unstemmed ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title_short ZnO Nanoparticles for Photocatalytic Application in Alkali-Activated Materials
title_sort zno nanoparticles for photocatalytic application in alkali-activated materials
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7728076/
https://www.ncbi.nlm.nih.gov/pubmed/33255643
http://dx.doi.org/10.3390/molecules25235519
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