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Isolation of a Nitromethane Anion in the Calix-Shaped Inorganic Cage
A calix-shaped polyoxometalate, [V(12)O(32)](4−) (V12), stabilizes an anion moiety in its central cavity. This molecule-sized container has the potential to control the reactivity of an anion. The highly-reactive cyanate is smoothly trapped by V12 to form [V(12)O(32)(CN)](5−). In the CH(3)NO(2) solu...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7729913/ https://www.ncbi.nlm.nih.gov/pubmed/33271966 http://dx.doi.org/10.3390/molecules25235670 |