Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison

The direct, one-pot oxidation of ethane to acetic acid was, for the first time, performed using a C-scorpionate complex anchored onto a magnetic core-shell support, the Fe(3)O(4)/TiO(2)/[FeCl(2){κ(3)-HC(pz)(3)}] composite. This catalytic system, where the magnetic catalyst is easily recovered and re...

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Detalles Bibliográficos
Autores principales: Matias, Inês A. S., Ribeiro, Ana P. C., Martins, Luísa M. D. R. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7731253/
https://www.ncbi.nlm.nih.gov/pubmed/33266077
http://dx.doi.org/10.3390/molecules25235642
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author Matias, Inês A. S.
Ribeiro, Ana P. C.
Martins, Luísa M. D. R. S.
author_facet Matias, Inês A. S.
Ribeiro, Ana P. C.
Martins, Luísa M. D. R. S.
author_sort Matias, Inês A. S.
collection PubMed
description The direct, one-pot oxidation of ethane to acetic acid was, for the first time, performed using a C-scorpionate complex anchored onto a magnetic core-shell support, the Fe(3)O(4)/TiO(2)/[FeCl(2){κ(3)-HC(pz)(3)}] composite. This catalytic system, where the magnetic catalyst is easily recovered and reused, is highly selective to the acetic acid synthesis. The performed green metrics calculations highlight the “greeness” of the new ethane oxidation procedure.
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spelling pubmed-77312532020-12-12 Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison Matias, Inês A. S. Ribeiro, Ana P. C. Martins, Luísa M. D. R. S. Molecules Article The direct, one-pot oxidation of ethane to acetic acid was, for the first time, performed using a C-scorpionate complex anchored onto a magnetic core-shell support, the Fe(3)O(4)/TiO(2)/[FeCl(2){κ(3)-HC(pz)(3)}] composite. This catalytic system, where the magnetic catalyst is easily recovered and reused, is highly selective to the acetic acid synthesis. The performed green metrics calculations highlight the “greeness” of the new ethane oxidation procedure. MDPI 2020-11-30 /pmc/articles/PMC7731253/ /pubmed/33266077 http://dx.doi.org/10.3390/molecules25235642 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Matias, Inês A. S.
Ribeiro, Ana P. C.
Martins, Luísa M. D. R. S.
Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title_full Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title_fullStr Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title_full_unstemmed Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title_short Selective Oxidation of Ethane to Acetic Acid Catalyzed by a C-Scorpionate Iron(II) Complex: A Homogeneous vs. Heterogeneous Comparison
title_sort selective oxidation of ethane to acetic acid catalyzed by a c-scorpionate iron(ii) complex: a homogeneous vs. heterogeneous comparison
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7731253/
https://www.ncbi.nlm.nih.gov/pubmed/33266077
http://dx.doi.org/10.3390/molecules25235642
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AT ribeiroanapc selectiveoxidationofethanetoaceticacidcatalyzedbyacscorpionateironiicomplexahomogeneousvsheterogeneouscomparison
AT martinsluisamdrs selectiveoxidationofethanetoaceticacidcatalyzedbyacscorpionateironiicomplexahomogeneousvsheterogeneouscomparison

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