Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses

Selectivity in N–H and S–H carbene insertion reactions promoted by Ru(II)porphyrinates currently requires slow addition of the diazo precursor and large excess of the primary amine and thiol substrates in the reaction medium. Such conditions are necessary to avoid the undesirable carbene coupling an...

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Detalles Bibliográficos
Autores principales: Fontana, Liniquer A., Almeida, Marlon P., Alcântara, Arthur F. P., Rigolin, Vitor H., Ribeiro, Marcos A., Barros, Wdeson P., Megiatto, Jackson D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7733472/
https://www.ncbi.nlm.nih.gov/pubmed/33311502
http://dx.doi.org/10.1038/s41467-020-20046-x

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