Application of Green Solvents: PEG and scCO(2) in the Mono- or Biphasic Catalytic Systems for the Repetitive Batch Coupling of Vinylsilanes with Vinyl Boronates toward 1-Boryl-1-silylethenes

[Image: see text] A new method for the repetitive batch silylative coupling (trans-silylation) of vinylsilanes with vinyl boronates in the presence of Ru(CO)Cl(H)(PCy(3))(2) immobilized in poly(ethylene glycols) (PEGs) has been developed. Three PEGs (PEG600, PEG2000, and MPEG2000) with different mol...

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Detalles Bibliográficos
Autores principales: Ludwiczak, Monika, Szyling, Jakub, Garbicz, Adriana, Sokolnicki, Tomasz, Pyziak, Jadwiga, Walkowiak, Jȩdrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735702/
https://www.ncbi.nlm.nih.gov/pubmed/33232139
http://dx.doi.org/10.1021/acs.inorgchem.0c02796

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735702/
https://www.ncbi.nlm.nih.gov/pubmed/33232139
http://dx.doi.org/10.1021/acs.inorgchem.0c02796

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