Diradical Character of Neutral Heteroleptic Bis(1,2-dithiolene) Metal Complexes: Case Study of [Pd(Me(2)timdt)(mnt)] (Me(2)timdt = 1,3-Dimethyl-2,4,5-trithioxoimidazolidine; mnt(2–) = 1,2-Dicyano-1,2-ethylenedithiolate)

[Image: see text] The reaction of the bis(1,2-dithiolene) complex [Pd(Me(2)timdt)(2)] (1; Me(2)timdt(•–) = monoreduced 1,3-dimethyl-2,4,5-trithioxoimidazolidine) with Br(2) yielded the complex [Pd(Me(2)timdt)Br(2)] (2), which was reacted with Na(2)mnt (mnt(2–) = 1,2-dicyano-1,2-ethylenedithiolate) t...

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Detalles Bibliográficos
Autores principales: Aragoni, M. Carla, Caltagirone, Claudia, Lippolis, Vito, Podda, Enrico, Slawin, Alexandra M. Z., Woollins, J. Derek, Pintus, Anna, Arca, Massimiliano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735710/
https://www.ncbi.nlm.nih.gov/pubmed/33185438
http://dx.doi.org/10.1021/acs.inorgchem.0c02696

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