Cargando…

Computational Studies of Chiral Hydroxyl Carboxylic Acids: The Allylboration of Aldehydes

[Image: see text] The mechanism of the asymmetric BINOL-derived hydroxyl carboxylic acid catalyzed allylboration of benzaldehyde was investigated using density functional theory calculations. A new reaction model is proposed, and the roles of the two Brønsted acidic sites of the catalyst elucidated....

Descripción completa

Detalles Bibliográficos
Autores principales: Farrar, Elliot H. E., Grayson, Matthew N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735727/
https://www.ncbi.nlm.nih.gov/pubmed/33227201
http://dx.doi.org/10.1021/acs.joc.0c02226

Ejemplares similares