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Computational Studies of Chiral Hydroxyl Carboxylic Acids: The Allylboration of Aldehydes
[Image: see text] The mechanism of the asymmetric BINOL-derived hydroxyl carboxylic acid catalyzed allylboration of benzaldehyde was investigated using density functional theory calculations. A new reaction model is proposed, and the roles of the two Brønsted acidic sites of the catalyst elucidated....
Autores principales: | Farrar, Elliot H. E., Grayson, Matthew N. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735727/ https://www.ncbi.nlm.nih.gov/pubmed/33227201 http://dx.doi.org/10.1021/acs.joc.0c02226 |
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