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Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe(2))(2) by Amine‐Exchange Reaction
The rare‐earth metal complexes Ln(L(1))[N(SiHMe(2))(2)](thf) (Ln=La, Ce, Y; L(1)=N,N′′‐bis(pentafluorophenyl)diethylenetriamine dianion) were synthesized by treating Ln[N(SiHMe(2))(2)](3)(thf)(2) with L(1)H(2). The lanthanum and cerium derivatives are active catalysts for the hydrosilylation of benz...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7745047/ https://www.ncbi.nlm.nih.gov/pubmed/32634253 http://dx.doi.org/10.1002/chem.202002011 |