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A Computational and Experimental Investigation of the Origin of Selectivity in the Chiral Phosphoric Acid Catalyzed Enantioselective Minisci Reaction
[Image: see text] The Minisci reaction is one of the most valuable methods for directly functionalizing basic heteroarenes to form carbon–carbon bonds. Use of prochiral, heteroatom-substituted radicals results in stereocenters being formed adjacent to the heteroaromatic system, generating motifs whi...
Autores principales: | Ermanis, Kristaps, Colgan, Avene C., Proctor, Rupert S. J., Hadrys, Barbara W., Phipps, Robert J., Goodman, Jonathan M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7747223/ https://www.ncbi.nlm.nih.gov/pubmed/33252228 http://dx.doi.org/10.1021/jacs.0c09668 |
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