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Catalytic generation of alkoxy radicals from unfunctionalized alcohols

Alkoxy radicals have long been recognized as powerful synthetic intermediates with well-established reactivity patterns. Due to the high bond dissociation free energy of aliphatic alcohol O–H bonds, these radicals are difficult to access through direct homolysis, and conventional methods have instea...

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Detalles Bibliográficos
Autores principales: Tsui, Elaine, Wang, Huaiju, Knowles, Robert R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7747465/
https://www.ncbi.nlm.nih.gov/pubmed/33384861
http://dx.doi.org/10.1039/d0sc04542j

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