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Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties
In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a–3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases ( 2a – 2d ) having different terminal groups (H, F, Cl, and Br). The products ( 3a – 3d ) were characterized b...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Scientific and Technological Research Council of Turkey
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7751826/ https://www.ncbi.nlm.nih.gov/pubmed/33488141 http://dx.doi.org/10.3906/kim-1905-60 |
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author | DOĞAN, Semih TÜMAY, Süreyya Oğuz MUTLU BALCI, Ceylan YEŞİLOT, Serkan BEŞLİ, Serap |
author_facet | DOĞAN, Semih TÜMAY, Süreyya Oğuz MUTLU BALCI, Ceylan YEŞİLOT, Serkan BEŞLİ, Serap |
author_sort | DOĞAN, Semih |
collection | PubMed |
description | In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a–3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases ( 2a – 2d ) having different terminal groups (H, F, Cl, and Br). The products ( 3a – 3d ) were characterized by elemental and mass analyses, FT-IR, and (1) H, (13) C, and (31) P NMR spectroscopies. Furthermore, the structure of compound 3a was also determined by X-ray crystallography. The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds ( 3a – 3d ) were investigated and the results were compared in the series. |
format | Online Article Text |
id | pubmed-7751826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | The Scientific and Technological Research Council of Turkey |
record_format | MEDLINE/PubMed |
spelling | pubmed-77518262021-01-22 Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties DOĞAN, Semih TÜMAY, Süreyya Oğuz MUTLU BALCI, Ceylan YEŞİLOT, Serkan BEŞLİ, Serap Turk J Chem Article In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a–3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases ( 2a – 2d ) having different terminal groups (H, F, Cl, and Br). The products ( 3a – 3d ) were characterized by elemental and mass analyses, FT-IR, and (1) H, (13) C, and (31) P NMR spectroscopies. Furthermore, the structure of compound 3a was also determined by X-ray crystallography. The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds ( 3a – 3d ) were investigated and the results were compared in the series. The Scientific and Technological Research Council of Turkey 2020-02-11 /pmc/articles/PMC7751826/ /pubmed/33488141 http://dx.doi.org/10.3906/kim-1905-60 Text en Copyright © 2020 The Author(s) This article is distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0/ ), which permits unrestricted use and redistribution provided that the original author and source are credited. |
spellingShingle | Article DOĞAN, Semih TÜMAY, Süreyya Oğuz MUTLU BALCI, Ceylan YEŞİLOT, Serkan BEŞLİ, Serap Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title | Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title_full | Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title_fullStr | Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title_full_unstemmed | Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title_short | Synthesis of new cyclotriphosphazene derivatives bearing Schiff bases and their thermal and absorbance properties |
title_sort | synthesis of new cyclotriphosphazene derivatives bearing schiff bases and their thermal and absorbance properties |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7751826/ https://www.ncbi.nlm.nih.gov/pubmed/33488141 http://dx.doi.org/10.3906/kim-1905-60 |
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