Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway

The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N -chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities...

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Autores principales: SHARMA, Priyamvada, SAILANI, Riya, MEENA, Anita, KHANDELWAL, Chandra Lata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Scientific and Technological Research Council of Turkey 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7751934/
https://www.ncbi.nlm.nih.gov/pubmed/33488205
http://dx.doi.org/10.3906/kim-2003-67
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author SHARMA, Priyamvada
SAILANI, Riya
MEENA, Anita
KHANDELWAL, Chandra Lata
author_facet SHARMA, Priyamvada
SAILANI, Riya
MEENA, Anita
KHANDELWAL, Chandra Lata
author_sort SHARMA, Priyamvada
collection PubMed
description The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N -chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested.
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spelling pubmed-77519342021-01-22 Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway SHARMA, Priyamvada SAILANI, Riya MEENA, Anita KHANDELWAL, Chandra Lata Turk J Chem Article The kinetic pathway of oxidation of crotyl alcohol by sodium salt of N -chloro-4-methylbenzene sulphonamide (chloramine-T) in acidic and alkaline medium has been studied. The speciation of chloramine-T has been made to suggest a proper and reasonable reaction mechanism. The thermodynamic quantities such as activation energy and activation entropy are evaluated in acidic as well as in catalysed alkaline medium. An anticipated reaction mechanism has been suggested. The Scientific and Technological Research Council of Turkey 2020-08-18 /pmc/articles/PMC7751934/ /pubmed/33488205 http://dx.doi.org/10.3906/kim-2003-67 Text en Copyright © 2020 The Author(s) This article is distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0/ ), which permits unrestricted use and redistribution provided that the original author and source are credited.
spellingShingle Article
SHARMA, Priyamvada
SAILANI, Riya
MEENA, Anita
KHANDELWAL, Chandra Lata
Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title_full Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title_fullStr Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title_full_unstemmed Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title_short Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway
title_sort oxidation of crotyl alcohol by n-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(viii) catalyst-a kinetic pathway
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7751934/
https://www.ncbi.nlm.nih.gov/pubmed/33488205
http://dx.doi.org/10.3906/kim-2003-67
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