Amine–borane complex-initiated SF(5)Cl radical addition on alkenes and alkynes

The SF(5)Cl radical addition on unsaturated compounds was performed using an air-stable amine–borane complex as the radical initiator. This method showed to be complementary to the classic Et(3)B-mediated SF(5)Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives w...

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Detalles Bibliográficos
Autores principales: Gilbert, Audrey, Langowski, Pauline, Delgado, Marine, Chabaud, Laurent, Pucheault, Mathieu, Paquin, Jean-François
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7753108/
https://www.ncbi.nlm.nih.gov/pubmed/33414854
http://dx.doi.org/10.3762/bjoc.16.256
Descripción
Sumario:The SF(5)Cl radical addition on unsaturated compounds was performed using an air-stable amine–borane complex as the radical initiator. This method showed to be complementary to the classic Et(3)B-mediated SF(5)Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.

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