Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology

Approximate analytical solutions for the overall adsorption functions based on the Fowler-Guggenheim local isotherm with a patchwise topology of adsorption centres location and four different adsorption heat distribution functions have been obtained. The Gaussian, constant, linear (as a particular c...

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Detalles Bibliográficos
Autores principales: Vigdorowitsch, Michael, Tsygankova, Liudmila E., Tanygina, Elena D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7753133/
https://www.ncbi.nlm.nih.gov/pubmed/33364502
http://dx.doi.org/10.1016/j.heliyon.2020.e05738
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author Vigdorowitsch, Michael
Tsygankova, Liudmila E.
Tanygina, Elena D.
author_facet Vigdorowitsch, Michael
Tsygankova, Liudmila E.
Tanygina, Elena D.
author_sort Vigdorowitsch, Michael
collection PubMed
description Approximate analytical solutions for the overall adsorption functions based on the Fowler-Guggenheim local isotherm with a patchwise topology of adsorption centres location and four different adsorption heat distribution functions have been obtained. The Gaussian, constant, linear (as a particular case of power distribution), and exponential distribution functions have been applied. Overall adsorption functions have been analytically obtained, studied and commented. The Gaussian-related adsorption function reproduces the classic computational result nearly perfectly.
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spelling pubmed-77531332020-12-23 Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology Vigdorowitsch, Michael Tsygankova, Liudmila E. Tanygina, Elena D. Heliyon Research Article Approximate analytical solutions for the overall adsorption functions based on the Fowler-Guggenheim local isotherm with a patchwise topology of adsorption centres location and four different adsorption heat distribution functions have been obtained. The Gaussian, constant, linear (as a particular case of power distribution), and exponential distribution functions have been applied. Overall adsorption functions have been analytically obtained, studied and commented. The Gaussian-related adsorption function reproduces the classic computational result nearly perfectly. Elsevier 2020-12-18 /pmc/articles/PMC7753133/ /pubmed/33364502 http://dx.doi.org/10.1016/j.heliyon.2020.e05738 Text en © 2020 The Author(s) http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Vigdorowitsch, Michael
Tsygankova, Liudmila E.
Tanygina, Elena D.
Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title_full Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title_fullStr Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title_full_unstemmed Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title_short Approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
title_sort approximate analytical overall isotherms: lateral interactions of adsorbate species and patchwise topology
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7753133/
https://www.ncbi.nlm.nih.gov/pubmed/33364502
http://dx.doi.org/10.1016/j.heliyon.2020.e05738
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AT tsygankovaliudmilae approximateanalyticaloverallisothermslateralinteractionsofadsorbatespeciesandpatchwisetopology
AT tanyginaelenad approximateanalyticaloverallisothermslateralinteractionsofadsorbatespeciesandpatchwisetopology

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