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Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes

Cobalt(II) alkyl complexes supported by a monoanionic NNN pincer ligand are pre‐catalysts for the regioselective hydroboration of terminal alkynes, yielding the Markovnikov products with α:β‐(E) ratios of up to 97:3. A cobalt(II) hydride and a cobalt(II) vinyl complex appear to determine the main re...

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Detalles Bibliográficos
Autores principales:	Blasius, Clemens K., Vasilenko, Vladislav, Matveeva, Regina, Wadepohl, Hubert, Gade, Lutz H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756293/ https://www.ncbi.nlm.nih.gov/pubmed/32889757 http://dx.doi.org/10.1002/anie.202009625

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