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(183)W NMR Spectroscopy Guides the Search for Tungsten Alkylidyne Catalysts for Alkyne Metathesis
Triarylsilanolates are privileged ancillary ligands for molybdenum alkylidyne catalysts for alkyne metathesis but lead to disappointing results and poor stability in the tungsten series. (1)H,(183)W heteronuclear multiple bond correlation spectroscopy, exploiting a favorable (5) J‐coupling between t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756321/ https://www.ncbi.nlm.nih.gov/pubmed/32820864 http://dx.doi.org/10.1002/anie.202009975 |