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[Si(O(2)C(6)F(4))(2)](14): Self‐Assembly of a Giant Perfluorinated Macrocyclic Host by Low‐Barrier Si−O Bond Metathesis
The dynamic covalent self‐assembly of 14 units of bis(perfluorocatecholato)silane leads to [Si(O(2)C(6)F(4))(2)](14)—the first giant perfluorinated macrocycle. The oligomerization process is monitored spectroscopically, and the macrocycle analyzed by single‐crystal X‐ray diffraction. The molecule fo...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756369/ https://www.ncbi.nlm.nih.gov/pubmed/32786036 http://dx.doi.org/10.1002/anie.202009942 |