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Unraveling the Mechanism of the Ir(III)‐Catalyzed Regiospecific Synthesis of α‐Chlorocarbonyl Compounds from Allylic Alcohols

We have used experimental studies and DFT calculations to investigate the Ir(III)‐catalyzed isomerization of allylic alcohols into carbonyl compounds, and the regiospecific isomerization–chlorination of allylic alcohols into α‐chlorinated carbonyl compounds. The mechanism involves a hydride eliminat...

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Detalles Bibliográficos
Autores principales:	Li, Man, Sanz‐Marco, Amparo, Martinez‐Erro, Samuel, García‐Vázquez, Víctor, Mai, Binh Khanh, Fernández‐Gallardo, Jacob, Himo, Fahmi, Martín‐Matute, Belén
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756427/ https://www.ncbi.nlm.nih.gov/pubmed/32757212 http://dx.doi.org/10.1002/chem.202002845

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