Cargando…

A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air

We report a new air‐stable Pd(I) dimer, [Pd(μ‐I)(PCy(2) (t)Bu)](2), which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kundu, Gourab, Sperger, Theresa, Rissanen, Kari, Schoenebeck, Franziska
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756449/ https://www.ncbi.nlm.nih.gov/pubmed/32810335 http://dx.doi.org/10.1002/anie.202009115

Ejemplares similares

Air‐Stable Pd(I) Dimer Enabled Remote Functionalization: Access to Fluorinated 1,1‐Diaryl Alkanes with Unprecedented Speed
por: Kundu, Gourab, et al.
Publicado: (2021)

Selective ortho‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer
por: Kalvet, Indrek, et al.
Publicado: (2020)

Palladium(I) Dimer Enabled Extremely Rapid and Chemoselective Alkylation of Aryl Bromides over Triflates and Chlorides in Air
por: Kalvet, Indrek, et al.
Publicado: (2017)

Rapid and Modular Access to Vinyl Cyclopropanes Enabled by Air‐stable Palladium(I) Dimer Catalysis
por: Mendel, Marvin, et al.
Publicado: (2023)

Catalysis with Palladium(I) Dimers
por: Fricke, Christoph, et al.
Publicado: (2020)

Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp(2)) and C(sp(3)) Coupling of C−Br, C−OTf, and C−Cl Bonds Enabled by a Single Palladium(I) Dimer
por: Keaveney, Sinead T., et al.
Publicado: (2018)

Site‐Selective C−S Bond Formation at C−Br over C−OTf and C−Cl Enabled by an Air‐Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst
por: Scattolin, Thomas, et al.
Publicado: (2018)

A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
por: Magnin, Guillaume, et al.
Publicado: (2019)

Rapid Room‐Temperature, Chemoselective C [Formula: see text] −C [Formula: see text] Coupling of Poly(pseudo)halogenated Arenes Enabled by Palladium(I) Catalysis in Air
por: Kalvet, Indrek, et al.
Publicado: (2016)

Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO(2)F) Enabled by an Air‐Stable Pd(I) Dimer
por: Mendel, Marvin, et al.
Publicado: (2019)

Thioether-enabled palladium-catalyzed atroposelective C–H olefination for N–C and C–C axial chirality
por: Li, Yanjun, et al.
Publicado: (2022)

Mechanistic insights on the Pd-catalyzed addition of C–X bonds across alkynes – a combined experimental and computational study
por: Sperger, Theresa, et al.
Publicado: (2017)

Selective Synthesis of Z-Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones
por: Guven, Sinem, et al.
Publicado: (2021)

Olefin metathesis in air
por: Piola, Lorenzo, et al.
Publicado: (2015)

A magnetically retrievable air and moisture stable gold and palladium nanocatalyst for efficient C−C coupling reactions
por: Goonesinghe, Chatura, et al.
Publicado: (2020)

Palladium‐Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides
por: Keaveney, Sinead T., et al.
Publicado: (2018)

Palladium-catalyzed C–H olefination of uridine, deoxyuridine, uridine monophosphate and uridine analogues
por: Zhao, Qin, et al.
Publicado: (2022)

Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
por: Lu, Yi, et al.
Publicado: (2015)

Mechanistic studies of the palladium-catalyzed S,O-ligand promoted C–H olefination of aromatic compounds
por: Naksomboon, Kananat, et al.
Publicado: (2023)

Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear Pd(I) Catalysis
por: Chen, Xiang‐Yu, et al.
Publicado: (2019)

Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives
por: Tomasek, Jasmine, et al.
Publicado: (2015)

Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion
por: Qiu, Youai, et al.
Publicado: (2017)

Kinetic Resolution of β-Alkyl Phenylethylamine Derivatives through Palladium-Catalyzed, Nosylamide-Directed C−H Olefination
por: Zhao, Zeng, et al.
Publicado: (2023)

Long-Range Olefin Isomerization Catalyzed by Palladium(0) Nanoparticles
por: Chuc, Le Thi Ngoc, et al.
Publicado: (2017)

Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes
por: Lu, Ming-Zhu, et al.
Publicado: (2017)

Macrocyclization of peptidoarylacetamides with self-assembly properties through late-stage palladium-catalyzed C(sp(2))▬H olefination
por: Tan, Jiantao, et al.
Publicado: (2019)

Palladium-Catalyzed C2-Selective Oxidative Olefination of Benzo[b]thiophene 1,1-Dioxides with Styrenes and Acrylates
por: Yang, Bingbin, et al.
Publicado: (2023)

Ligand‐Enabled γ‐C(sp(3))−H Olefination of Free Carboxylic Acids
por: Ghosh, Kiron Kumar, et al.
Publicado: (2020)

Charge-controlled Pd catalysis enables the meta-C–H activation and olefination of arenes
por: Mondal, Arup, et al.
Publicado: (2023)

Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
por: Zhu, Can, et al.
Publicado: (2015)

Air-stable, recyclable, and time-efficient diphenylphosphinite cellulose-supported palladium nanoparticles as a catalyst for Suzuki–Miyaura reactions
por: Du, Qingwei, et al.
Publicado: (2011)

Modular and Selective Arylation of Aryl Germanes (C−GeEt(3)) over C−Bpin, C−SiR(3) and Halogens Enabled by Light‐Activated Gold Catalysis
por: Sherborne, Grant J., et al.
Publicado: (2020)

[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ(3) P,C (1),P′](trifluoroacetato)palladium(II)
por: Johnson, Magnus T., et al.
Publicado: (2010)

Ligand-Enabled γ-C–H Olefination and Carbonylation: Construction of β-Quaternary Carbon Centers
por: Li, Suhua, et al.
Publicado: (2014)

Toward Green Acylation of (Hetero)arenes: Palladium-Catalyzed Carbonylation of Olefins to Ketones
por: Liu, Jie, et al.
Publicado: (2017)

Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl
por: Richardson, Georgia M., et al.
Publicado: (2021)

Simplifying the Synthesis of Nonproteinogenic Amino Acids via Palladium-Catalyzed δ-Methyl C–H Olefination of Aliphatic Amines and Amino Acids
por: Bhattacharya, Trisha, et al.
Publicado: (2023)

Stable Monoareno-pentalenes with Two Olefinic Protons
por: Mayer, Péter J., et al.
Publicado: (2022)

An Air‐Stable Heterobimetallic Si(2)M(2) Tetrahedral Cluster
por: Dübek, Gizem, et al.
Publicado: (2020)

Development of an IoT-Enabled Air Pollution Monitoring and Air Purifier System
por: Anitha, M., et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_085cgside2k5drt2r3i14ekec2