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Synthesis, Electronic Properties and Reactivity of [B(12)X(11)(NO(2))](2−) (X=F–I) Dianions

Nitro‐functionalized undecahalogenated closo‐dodecaborates [B(12)X(11)(NO(2))](2−) were synthesized in high purities and characterized by NMR, IR, and Raman spectroscopy, single crystal X‐diffraction, mass spectrometry, and gas‐phase ion vibrational spectroscopy. The NO(2) substituent leads to an en...

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Detalles Bibliográficos
Autores principales:	Asmis, Knut R., Beele, Björn B., Jenne, Carsten, Kawa, Sebastian, Knorke, Harald, Nierstenhöfer, Marc C., Wang, Xue‐Bin, Warneke, Jonas, Warneke, Ziyan, Yuan, Qinqin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756457/ https://www.ncbi.nlm.nih.gov/pubmed/33017100 http://dx.doi.org/10.1002/chem.202003537

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