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Synthesis and Reactivity of Bis(silylene)‐Coordinated Calcium and Divalent Lanthanide Complexes

Divalent lanthanide complexes of Eu (1) and Yb (2) coordinated by a chelating pyridine‐based bis(silylene) ligand were isolated and fully characterized. Compared to the Eu(II) complex 1, the Yb(II) complex 2 presents a lower thermal stability, resulting in the activation of one Si(II)−N bond and for...

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Detalles Bibliográficos
Autores principales: Sun, Xiaofei, Simler, Thomas, Reiter, Kevin, Weigend, Florian, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756572/
https://www.ncbi.nlm.nih.gov/pubmed/32744765
http://dx.doi.org/10.1002/chem.202003417