Chalcogen‐Expanded Unsaturated Silicon Clusters: Thia‐, Selena‐, and Tellurasiliconoids

Reactions of silylenes with heavier chalcogens (E) typically result in Si=E double bonds or their π‐addition products. In contrast, the oxidation of a silylene‐functionalized unsaturated silicon cluster (siliconoid) with Group 16 elements selectively yields cluster expanded siliconoids Si(7)E (E=S,...

Descripción completa

Detalles Bibliográficos
Autores principales: Poitiers, Nadine E., Huch, Volker, Zimmer, Michael, Scheschkewitz, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756652/
https://www.ncbi.nlm.nih.gov/pubmed/32700779
http://dx.doi.org/10.1002/chem.202003180

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756652/
https://www.ncbi.nlm.nih.gov/pubmed/32700779
http://dx.doi.org/10.1002/chem.202003180

Ejemplares similares