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A Unified Framework for Understanding Nucleophilicity and Protophilicity in the S(N)2/E2 Competition
The concepts of nucleophilicity and protophilicity are fundamental and ubiquitous in chemistry. A case in point is bimolecular nucleophilic substitution (S(N)2) and base‐induced elimination (E2). A Lewis base acting as a strong nucleophile is needed for S(N)2 reactions, whereas a Lewis base acting a...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756690/ https://www.ncbi.nlm.nih.gov/pubmed/32866336 http://dx.doi.org/10.1002/chem.202003831 |