Functionalization of N(2) via Formal 1,3‐Haloboration of a Tungsten(0) σ‐Dinitrogen Complex

Boron tribromide and aryldihaloboranes were found to undergo 1,3‐haloboration across one W−N≡N moiety of a group 6 end‐on dinitrogen complex (i.e. trans‐[W(N(2))(2)(dppe)(2)]). The N‐borylated products consist of a reduced diazenido unit sandwiched between a W(II) center and a trivalent boron substi...

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Detalles Bibliográficos
Autores principales: Rempel, Anna, Mellerup, Soren K., Fantuzzi, Felipe, Herzog, Anselm, Deißenberger, Andrea, Bertermann, Rüdiger, Engels, Bernd, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756771/
https://www.ncbi.nlm.nih.gov/pubmed/32957161
http://dx.doi.org/10.1002/chem.202002678

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756771/
https://www.ncbi.nlm.nih.gov/pubmed/32957161
http://dx.doi.org/10.1002/chem.202002678

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