Cargando…
Functionalization of N(2) via Formal 1,3‐Haloboration of a Tungsten(0) σ‐Dinitrogen Complex
Boron tribromide and aryldihaloboranes were found to undergo 1,3‐haloboration across one W−N≡N moiety of a group 6 end‐on dinitrogen complex (i.e. trans‐[W(N(2))(2)(dppe)(2)]). The N‐borylated products consist of a reduced diazenido unit sandwiched between a W(II) center and a trivalent boron substi...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756771/ https://www.ncbi.nlm.nih.gov/pubmed/32957161 http://dx.doi.org/10.1002/chem.202002678 |