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Nature and Strength of Lewis Acid/Base Interaction in Boron and Nitrogen Trihalides

We have quantum chemically investigated the bonding between archetypical Lewis acids and bases. Our state‐of‐the‐art computations on the X(3)B−NY(3) Lewis pairs have revealed the origin behind the systematic increase in B−N bond strength as X and Y are varied from F to Cl, Br, I, H. For H(3)B−NY(3),...

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Detalles Bibliográficos
Autores principales: Rodrigues Silva, Daniela, de Azevedo Santos, Lucas, Freitas, Matheus P., Guerra, Célia Fonseca, Hamlin, Trevor A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756781/
https://www.ncbi.nlm.nih.gov/pubmed/33015969
http://dx.doi.org/10.1002/asia.202001127