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Synthetic C6‐Functionalized Aminoflavin Catalysts Enable Aerobic Bromination of Oxidation‐Prone Substrates
Flavoenzymes catalyze oxidations via hydroperoxide intermediates that result from activation of molecular O(2). These reactions—such as hydroxylation and halogenation—depend on the additional catalytic activity of functional groups in the peptide environment of the flavin cofactor. We report synthet...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756793/ https://www.ncbi.nlm.nih.gov/pubmed/32790228 http://dx.doi.org/10.1002/anie.202009657 |