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New Reactivity Patterns in 3H‐Phosphaallene Chemistry [Aryl‐P=C=C(H)‐tBu]: Hydroboration of the C=C Bond, Deprotonation and Trimerisation

3H‐Phosphaallenes, R−P=C=C(H)C−R’ (3), are accessible in a multigram scale on a new and facile route and show a fascinating chemical reactivity. BH(3)(SMe(2)) and 3 a (R=Mes*, R’=tBu) afforded by hydroboration of the C=C bonds of two phosphaallene molecules an unprecedented borane (7) with the B ato...

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Detalles Bibliográficos
Autores principales:	Tendyck, Jonas C., Hepp, Alexander, Würthwein, Ernst‐Ulrich, Uhl, Werner
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756809/ https://www.ncbi.nlm.nih.gov/pubmed/32618025 http://dx.doi.org/10.1002/chem.202002506

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