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Enantiomerically Pure Constrained Geometry Complexes of the Rare‐Earth Metals Featuring a Dianionic N‐Donor Functionalised Pentadienyl Ligand: Synthesis and Characterisation

We report the preparation of enantiomerically pure constrained geometry complexes (cgc) of the rare‐earth metals bearing a pentadienyl moiety (pdl) derived from the natural product (1R)‐(−)‐myrtenal. The potassium salt 1, [Kpdl*], was treated with ClSiMe(2)NHtBu, and the resulting pentadiene 2 was d...

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Detalles Bibliográficos
Autores principales:	Münster, Katharina, Fecker, Ann Christin, Raeder, Jan, Freytag, Matthias, Jones, Peter G., Walter, Marc D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756846/ https://www.ncbi.nlm.nih.gov/pubmed/32735382 http://dx.doi.org/10.1002/chem.202003170

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