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Experimental and Computational Studies on a Base‐Free Terminal Uranium Phosphinidene Metallocene

The first stable base‐free terminal uranium phosphinidene metallocene is presented; and its structure and reactivity have been studied in detail and compared to that of the corresponding thorium derivative. Salt metathesis reaction of the methyl iodide uranium metallocene Cp’’’(2)U(I)Me (2, Cp’’’=η...

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Detalles Bibliográficos
Autores principales: Wang, Deqiang, Ding, Wanjian, Hou, Guohua, Zi, Guofu, Walter, Marc D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756876/
https://www.ncbi.nlm.nih.gov/pubmed/32744750
http://dx.doi.org/10.1002/chem.202003465