Cargando…
Study of Thermodynamic and Acoustic Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol at Different Temperatures
[Image: see text] The densities and speed of sound for liquid mixtures containing vitamin B(3) (niacin) at 0.01, 0.03, and 0.05 mol·kg(–1) concentrations in aqueous propylene glycol and hexylene glycol at the variation of temperatures from 293.15 to 308.15 K have been measured using an Anton Paar DS...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7758894/ https://www.ncbi.nlm.nih.gov/pubmed/33376872 http://dx.doi.org/10.1021/acsomega.0c04292 |
_version_ | 1783627021175226368 |
---|---|
author | Chakraborty, Nabaparna Juglan, Kailash Chandra Kumar, Harsh |
author_facet | Chakraborty, Nabaparna Juglan, Kailash Chandra Kumar, Harsh |
author_sort | Chakraborty, Nabaparna |
collection | PubMed |
description | [Image: see text] The densities and speed of sound for liquid mixtures containing vitamin B(3) (niacin) at 0.01, 0.03, and 0.05 mol·kg(–1) concentrations in aqueous propylene glycol and hexylene glycol at the variation of temperatures from 293.15 to 308.15 K have been measured using an Anton Paar DSA 5000 M. From volumetric experimental data, apparent molar volume (V(ϕ)), partial molar volume (V(ϕ)(0)), and partial molar volume of transfer (ΔV(ϕ)(0)) are calculated along with the apparent molar isentropic compression (K(ϕ, S)), partial molar isentropic compression (K(ϕ, S)(0)), and partial molar isentropic compression of transfer (ΔK(ϕ)(0)) using experimental acoustic data. The positive volumetric data (i.e., apparent molar volume and partial molar volume) indicates strong solute–solvent interactions inside the mixture. Along with these values, the empirical constants a, b, and c with the pair and triplet coefficients (V(AB), V(ABB), K(AB), K(ABB)) are also calculated. |
format | Online Article Text |
id | pubmed-7758894 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-77588942020-12-28 Study of Thermodynamic and Acoustic Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol at Different Temperatures Chakraborty, Nabaparna Juglan, Kailash Chandra Kumar, Harsh ACS Omega [Image: see text] The densities and speed of sound for liquid mixtures containing vitamin B(3) (niacin) at 0.01, 0.03, and 0.05 mol·kg(–1) concentrations in aqueous propylene glycol and hexylene glycol at the variation of temperatures from 293.15 to 308.15 K have been measured using an Anton Paar DSA 5000 M. From volumetric experimental data, apparent molar volume (V(ϕ)), partial molar volume (V(ϕ)(0)), and partial molar volume of transfer (ΔV(ϕ)(0)) are calculated along with the apparent molar isentropic compression (K(ϕ, S)), partial molar isentropic compression (K(ϕ, S)(0)), and partial molar isentropic compression of transfer (ΔK(ϕ)(0)) using experimental acoustic data. The positive volumetric data (i.e., apparent molar volume and partial molar volume) indicates strong solute–solvent interactions inside the mixture. Along with these values, the empirical constants a, b, and c with the pair and triplet coefficients (V(AB), V(ABB), K(AB), K(ABB)) are also calculated. American Chemical Society 2020-12-07 /pmc/articles/PMC7758894/ /pubmed/33376872 http://dx.doi.org/10.1021/acsomega.0c04292 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
spellingShingle | Chakraborty, Nabaparna Juglan, Kailash Chandra Kumar, Harsh Study of Thermodynamic and Acoustic Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol at Different Temperatures |
title | Study of Thermodynamic and Acoustic
Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol
at Different Temperatures |
title_full | Study of Thermodynamic and Acoustic
Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol
at Different Temperatures |
title_fullStr | Study of Thermodynamic and Acoustic
Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol
at Different Temperatures |
title_full_unstemmed | Study of Thermodynamic and Acoustic
Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol
at Different Temperatures |
title_short | Study of Thermodynamic and Acoustic
Properties of Niacin in Aqueous Hexylene Glycol and Propylene Glycol
at Different Temperatures |
title_sort | study of thermodynamic and acoustic
properties of niacin in aqueous hexylene glycol and propylene glycol
at different temperatures |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7758894/ https://www.ncbi.nlm.nih.gov/pubmed/33376872 http://dx.doi.org/10.1021/acsomega.0c04292 |
work_keys_str_mv | AT chakrabortynabaparna studyofthermodynamicandacousticpropertiesofniacininaqueoushexyleneglycolandpropyleneglycolatdifferenttemperatures AT juglankailashchandra studyofthermodynamicandacousticpropertiesofniacininaqueoushexyleneglycolandpropyleneglycolatdifferenttemperatures AT kumarharsh studyofthermodynamicandacousticpropertiesofniacininaqueoushexyleneglycolandpropyleneglycolatdifferenttemperatures |