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Photo-oxidation and Thermal Oxidations of Triptycene Thiols by Aryl Chalcogen Oxides

[Image: see text] Oxidation of thiols yield sulfenic acids, which are very unstable intermediates. As sulfenic acids are reactive, they form disulfides in the presence of thiols. However, sulfenic acids also oxidize to sulfinic acids (−SO(2)H) and sulfonic acids (−SO(3)H) at higher concentrations of...

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Detalles Bibliográficos
Autores principales: Chintala, Satyanarayana M., Maness, Peter F., Petroff, John T., Throgmorton, John C., Zhang, Miao, Omlid, Sara M., McCulla, Ryan D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7758903/
https://www.ncbi.nlm.nih.gov/pubmed/33376871
http://dx.doi.org/10.1021/acsomega.0c04293