Cargando…

Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties

[Image: see text] Global warming has prompted a search for new materials that capture and sink carbon dioxide (CO(2)). Biochar is a derivative of biomass pyrolysis and a carbon sink mainly used to improve crop production. This work explores the underlying mechanism behind biochar’s electric conducti...

Descripción completa

Detalles Bibliográficos
Autores principales: Natalio, Filipe, Corrales, Tomas P., Feldman, Yishay, Lew, Beni, Graber, Ellen R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7758945/
https://www.ncbi.nlm.nih.gov/pubmed/33376886
http://dx.doi.org/10.1021/acsomega.0c04639
_version_ 1783627030352363520
author Natalio, Filipe
Corrales, Tomas P.
Feldman, Yishay
Lew, Beni
Graber, Ellen R.
author_facet Natalio, Filipe
Corrales, Tomas P.
Feldman, Yishay
Lew, Beni
Graber, Ellen R.
author_sort Natalio, Filipe
collection PubMed
description [Image: see text] Global warming has prompted a search for new materials that capture and sink carbon dioxide (CO(2)). Biochar is a derivative of biomass pyrolysis and a carbon sink mainly used to improve crop production. This work explores the underlying mechanism behind biochar’s electric conductivity using a wide range of feedstocks and its combination with a binder (gypsum). This gypsum–biochar composite exhibits decreased density and flexural moduli with increasing biochar content, particularly after 20% w/w. Gypsum–biochar drywall-like composite prototypes display increasing shielding efficiency mostly in the microwave range as a function of biochar content, differing from other conventional metal (copper) and synthetic carbon-based materials. This narrow range of electromagnetic interference (EMI) shielding is attributed to natural alignment (isotropy) of the carbon ultrastructure (e.g., lignin) induced by heat and intrinsic interconnectivity in addition to traditional phenomena such as dissipation of surface currents and polarization in the electric field. These biomass-derived products could be used as sustainable lightweight materials in a future bio-based economy.
format Online
Article
Text
id pubmed-7758945
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-77589452020-12-28 Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties Natalio, Filipe Corrales, Tomas P. Feldman, Yishay Lew, Beni Graber, Ellen R. ACS Omega [Image: see text] Global warming has prompted a search for new materials that capture and sink carbon dioxide (CO(2)). Biochar is a derivative of biomass pyrolysis and a carbon sink mainly used to improve crop production. This work explores the underlying mechanism behind biochar’s electric conductivity using a wide range of feedstocks and its combination with a binder (gypsum). This gypsum–biochar composite exhibits decreased density and flexural moduli with increasing biochar content, particularly after 20% w/w. Gypsum–biochar drywall-like composite prototypes display increasing shielding efficiency mostly in the microwave range as a function of biochar content, differing from other conventional metal (copper) and synthetic carbon-based materials. This narrow range of electromagnetic interference (EMI) shielding is attributed to natural alignment (isotropy) of the carbon ultrastructure (e.g., lignin) induced by heat and intrinsic interconnectivity in addition to traditional phenomena such as dissipation of surface currents and polarization in the electric field. These biomass-derived products could be used as sustainable lightweight materials in a future bio-based economy. American Chemical Society 2020-12-10 /pmc/articles/PMC7758945/ /pubmed/33376886 http://dx.doi.org/10.1021/acsomega.0c04639 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Natalio, Filipe
Corrales, Tomas P.
Feldman, Yishay
Lew, Beni
Graber, Ellen R.
Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title_full Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title_fullStr Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title_full_unstemmed Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title_short Sustainable Lightweight Biochar-Based Composites with Electromagnetic Shielding Properties
title_sort sustainable lightweight biochar-based composites with electromagnetic shielding properties
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7758945/
https://www.ncbi.nlm.nih.gov/pubmed/33376886
http://dx.doi.org/10.1021/acsomega.0c04639
work_keys_str_mv AT nataliofilipe sustainablelightweightbiocharbasedcompositeswithelectromagneticshieldingproperties
AT corralestomasp sustainablelightweightbiocharbasedcompositeswithelectromagneticshieldingproperties
AT feldmanyishay sustainablelightweightbiocharbasedcompositeswithelectromagneticshieldingproperties
AT lewbeni sustainablelightweightbiocharbasedcompositeswithelectromagneticshieldingproperties
AT graberellenr sustainablelightweightbiocharbasedcompositeswithelectromagneticshieldingproperties