Polydimethylsiloxane Elastomers Filled with Rod-Like α-MnO(2) Nanoparticles: An Interplay of Structure and Electrorheological Performance

For the first time, electroactive nanocomposite elastomers based on polydimethylsiloxane and filled with rod-like α-MnO(2) nanoparticles have been obtained. The curing of the filled elastomer in an electric field, resulting in the ordering of the α-MnO(2) particles, had a significant effect on the degree of polymer crosslinking, as well as on the electrorheological characteristics of the nanocomposites obtained through this process, namely the values of the storage and loss moduli. The dielectric spectra of filled elastomers in the frequency range 25–10(6) Hz were analysed in terms of interfacial relaxation processes. It has been shown, for the first time, that the application of an electric field leads to a decrease in the value of the Payne effect in composite elastomers. Analysis of the rheological effect in the obtained materials has demonstrated the possibility of designing highly efficient electrorheological elastomers that change their elastic properties by 4.3 times in electric fields of up to 2 kV/mm.