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Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help?
Superglassy polymers have emerged as potential membrane materials for several gas separation applications, including acid gas removal from natural gas. Despite the superior performance shown at laboratory scale, their use at industrial scale is hampered by their large drop in gas permeability over t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7763000/ https://www.ncbi.nlm.nih.gov/pubmed/33322061 http://dx.doi.org/10.3390/membranes10120413 |
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author | Ameen, Ahmed W. Budd, Peter M. Gorgojo, Patricia |
author_facet | Ameen, Ahmed W. Budd, Peter M. Gorgojo, Patricia |
author_sort | Ameen, Ahmed W. |
collection | PubMed |
description | Superglassy polymers have emerged as potential membrane materials for several gas separation applications, including acid gas removal from natural gas. Despite the superior performance shown at laboratory scale, their use at industrial scale is hampered by their large drop in gas permeability over time due to physical aging. Several strategies are proposed in the literature to prevent loss of performance, the incorporation of fillers being a successful approach. In this work, we provide a comprehensive economic study on the application of superglassy membranes in a hybrid membrane/amine process for natural gas sweetening. The hybrid process is compared with the more traditional stand-alone amine-absorption technique for a range of membrane gas separation properties (CO(2) permeance and CO(2)/CH(4) selectivity), and recommendations for long-term membrane performance are made. These recommendations can drive future research on producing mixed matrix membranes (MMMs) of superglassy polymers with anti-aging properties (i.e., target permeance and selectivity is maintained over time), as thin film nanocomposite membranes (TFNs). For the selected natural gas composition of 28% of acid gas content (8% CO(2) and 20% H(2)S), we have found that a CO(2) permeance of 200 GPU and a CO(2)/CH(4) selectivity of 16 is an optimal target. |
format | Online Article Text |
id | pubmed-7763000 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-77630002020-12-27 Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? Ameen, Ahmed W. Budd, Peter M. Gorgojo, Patricia Membranes (Basel) Article Superglassy polymers have emerged as potential membrane materials for several gas separation applications, including acid gas removal from natural gas. Despite the superior performance shown at laboratory scale, their use at industrial scale is hampered by their large drop in gas permeability over time due to physical aging. Several strategies are proposed in the literature to prevent loss of performance, the incorporation of fillers being a successful approach. In this work, we provide a comprehensive economic study on the application of superglassy membranes in a hybrid membrane/amine process for natural gas sweetening. The hybrid process is compared with the more traditional stand-alone amine-absorption technique for a range of membrane gas separation properties (CO(2) permeance and CO(2)/CH(4) selectivity), and recommendations for long-term membrane performance are made. These recommendations can drive future research on producing mixed matrix membranes (MMMs) of superglassy polymers with anti-aging properties (i.e., target permeance and selectivity is maintained over time), as thin film nanocomposite membranes (TFNs). For the selected natural gas composition of 28% of acid gas content (8% CO(2) and 20% H(2)S), we have found that a CO(2) permeance of 200 GPU and a CO(2)/CH(4) selectivity of 16 is an optimal target. MDPI 2020-12-10 /pmc/articles/PMC7763000/ /pubmed/33322061 http://dx.doi.org/10.3390/membranes10120413 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ameen, Ahmed W. Budd, Peter M. Gorgojo, Patricia Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title | Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title_full | Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title_fullStr | Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title_full_unstemmed | Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title_short | Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help? |
title_sort | superglassy polymers to treat natural gas by hybrid membrane/amine processes: can fillers help? |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7763000/ https://www.ncbi.nlm.nih.gov/pubmed/33322061 http://dx.doi.org/10.3390/membranes10120413 |
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