Orientation of Poly(ε-caprolactone) in Its Poly(vinyl chloride) Blends Crystallized under Strain: The Role of Strain Rate

The blends of high and low molecular weights poly(ε-caprolactone) (PCL) with poly(vinyl chloride (PVC) were prepared. The samples before and after the crystallization of PCL were uniaxially stretched to different draw ratios. The orientation features of PCL in a stretched crystalline PCL/PVC blend and crystallized from the amorphous PCL/PVC blends under varied strains were studied by wide-angle X-ray diffraction (WAXD). It was found that a uniaxial stretching of crystalline PCL/PVC blend with high molecular weight PCL results in the c-axis orientation along the stretching direction, as is usually done for the PCL bulk sample. For the stretched amorphous PCL/PVC blend samples, the crystallization of high molecular weight PCL in the blends under a draw ratio of λ = 3 with a strain rate of 6 mm/min leads to a ring-fiber orientation. In the samples with draw ratios of λ = 4 and 5, the uniaxial orientation of a-, b-, and c-axes along the strain direction coexist after crystallization of high molecular weight PCL. With a draw ratio of λ = 6, mainly the b-axis orientation of high molecular weight PCL is identified. For the low molecular weight PCL, on the contrary, the ring-fiber and a-axis orientations coexist under a draw ratio of λ = 3. The a-axis orientation decreases with the increase of draw ratio. When the λ reaches 5, only a poorly oriented ring-fiber pattern has been recognized. These results are different from the similar samples stretched at a higher strain rate as reported in the literatures and demonstrate the important role of strain rate on the crystallization behavior of PCL in its blend with PVC under strain.