High-Performance Na-Ion Storage of S-Doped Porous Carbon Derived from Conjugated Microporous Polymers

Na-ion batteries (NIBs) have attracted considerable attention in recent years owing to the high abundance and low cost of Na. It is well known that S doping can improve the electrochemical performance of carbon materials for NIBs. However, the current methods for S doping in carbons normally involve toxic precursors or rigorous conditions. In this work, we report a creative and facile strategy for preparing S-doped porous carbons (SCs) via the pyrolysis of conjugated microporous polymers (CMPs). Briefly, thiophene-based CMPs served as the precursors and doping sources simultaneously. Simple direct carbonization of CMPs produced S-doped carbon materials with highly porous structures. When used as an anode for NIBs, the SCs exhibited a high reversible capacity of 440 mAh g(−1) at 50 mA g(−1) after 100 cycles, superior rate capability, and excellent cycling stability (297 mAh g(−1) after 1000 cycles at 500 mA g(−1)), outperforming most S-doped carbon materials reported thus far. The excellent performance of the SCs is attributed to the expanded lattice distance after S doping. Furthermore, we employed ex situ X-ray photoelectron spectroscopy to investigate the electrochemical reaction mechanism of the SCs during sodiation–desodiation, which can highlight the role of doped S for Na-ion storage. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-019-0291-z) contains supplementary material, which is available to authorized users.