Ultra-stable CsPbBr(3) Perovskite Nanosheets for X-Ray Imaging Screen

Wet chemistry methods, including hot-injection and precipitation methods, have emerged as major synthetic routes for high-quality perovskite nanocrystals in backlit display and scintillation applications. However, low chemical yield hinders their upscale production for practical use. Meanwhile, the labile nature of halide-based perovskite poses a major challenge for long-term storage of perovskite nanocrystals. Herein, we report a green synthesis at room temperature for gram-scale production of CsPbBr(3) nanosheets with minimum use of solvent, saving over 95% of the solvent for the unity mass nanocrystal production. The perovskite colloid exhibits record stability upon long-term storage for up to 8 months, preserving a photoluminescence quantum yield of 63% in solid state. Importantly, the colloidal nanosheets show self-assembly behavior upon slow solidification, generating a crack-free thin film in a large area. The uniform film was then demonstrated as an efficient scintillation screen for X-ray imaging. Our findings bring a scalable tool for synthesis of high-quality perovskite nanocrystals, which may inspire the industrial optoelectronic application of large-area perovskite film. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-019-0283-z) contains supplementary material, which is available to authorized users.