Layered Birnessite Cathode with a Displacement/Intercalation Mechanism for High-Performance Aqueous Zinc-Ion Batteries

Mn-based rechargeable aqueous zinc-ion batteries (ZIBs) are highly promising because of their high operating voltages, attractive energy densities, and eco-friendliness. However, the electrochemical performances of Mn-based cathodes usually suffer from their serious structure transformation upon charge/discharge cycling. Herein, we report a layered sodium-ion/crystal water co-intercalated Birnessite cathode with the formula of Na(0.55)Mn(2)O(4)·0.57H(2)O (NMOH) for high-performance aqueous ZIBs. A displacement/intercalation electrochemical mechanism was confirmed in the Mn-based cathode for the first time. Na(+) and crystal water enlarge the interlayer distance to enhance the insertion of Zn(2+), and some sodium ions are replaced with Zn(2+) in the first cycle to further stabilize the layered structure for subsequent reversible Zn(2+)/H(+) insertion/extraction, resulting in exceptional specific capacities and satisfactory structural stabilities. Additionally, a pseudo-capacitance derived from the surface-adsorbed Na(+) also contributes to the electrochemical performances. The NMOH cathode not only delivers high reversible capacities of 389.8 and 87.1 mA h g(−1) at current densities of 200 and 1500 mA g(−1), respectively, but also maintains a good long-cycling performance of 201.6 mA h g(−1) at a high current density of 500 mA g(−1) after 400 cycles, which makes the NMOH cathode competitive for practical applications. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-020-0397-3) contains supplementary material, which is available to authorized users.