Newly Design Porous/Sponge Red Phosphorus@Graphene and Highly Conductive Ni(2)P Electrode for Asymmetric Solid State Supercapacitive Device With Excellent Performance

Supercapacitors have attracted much attention in the field of electrochemical energy storage. However, material preparation, stability, performance as well as power density limit their applications in many fields. Herein, a sponge-like red phosphorus@graphene (rP@rGO) negative electrode and a Ni(2)P positive electrode were prepared using a simple one-step method. Both electrodes showed excellent performances (294 F g(−1) and 1526.6 F g(−1) for rP@rGO and Ni(2)P, respectively), which seem to be the highest among all rP@rGO- and Ni(2)P-based electrodes reported so far. The asymmetric solid-state supercapacitor was assembled by sandwiching a gel electrolyte-soaked cellulose paper between rP@rGO and Ni(2)P as the negative and positive electrodes. Compared to other asymmetric devices, the device, which attained a high operating window of up to 1.6 V, showed high energy and power density values of 41.66 and 1200 W kg(−1), respectively. It also has an excellent cyclic stability up to 88% after various consecutive charge/discharge tests. Additionally, the device could power commercial light emitting diodes and fans for 30 s. So, the ease of the synthesis method and excellent performance of the prepared electrode materials mat have significant potential for energy storage applications [Image: see text]. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-019-0360-3) contains supplementary material, which is available to authorized users.