Comprehensive Design of the High-Sulfur-Loading Li–S Battery Based on MXene Nanosheets

The lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density, but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architecture degradation. A comprehensive study of the sulfur host microstructure design and the cell architecture construction based on the MXene phase (Ti(3)C(2)T(x) nanosheets) is performed, aiming at realize stable cycling performance of Li–S battery with high sulfur areal loading. The interwoven KB@Ti(3)C(2)T(x) composite formed by self-assembly of MXene and Ktejen black, not only provides superior conductivity and maintains the electrode integrality bearing the volume expansion/shrinkage when used as the sulfur host, but also functions as an interlayer on separator to further retard the polysulfide cross-diffusion that possibly escaped from the cathode. The KB@Ti(3)C(2)T(x) interlayer is only 0.28 mg cm(−2) in areal loading and 3 μm in thickness, which accounts a little contribution to the thick sulfur electrode; thus, the impacts on the energy density is minimal. By coupling the robust KB@Ti(3)C(2)T(x) cathode and the effective KB@Ti(3)C(2)T(x) modified separator, a stable Li–S battery with high sulfur areal loading (5.6 mg cm(−2)) and high areal capacity (6.4 mAh cm(−2)) at relatively lean electrolyte is achieved. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-020-00449-7) contains supplementary material, which is available to authorized users.