Rational Design of Layered SnS(2) on Ultralight Graphene Fiber Fabrics as Binder-Free Anodes for Enhanced Practical Capacity of Sodium-Ion Batteries

Generally, the practical capacity of an electrode should include the weight of non-active components such as current collector, polymer binder, and conductive additives, which were as high as 70 wt% in current reported works, seriously limiting the practical capacity. This work pioneered the usage of ultralight reduced graphene fiber (rGF) fabrics as conductive scaffolds, aiming to reduce the weight of non-active components and enhance the practical capacity. Ultrathin SnS(2) nanosheets/rGF hybrids were prepared and used as binder-free electrodes of sodium-ion batteries (SIBs). The interfused graphene fibers endow the electrode a porous, continuous, and conductive network. The in situ phase transformation from SnO(2) to SnS(2) could preserve the strong interfacial interactions between SnS(2) and graphene. Benefitting from these, the designed binder-free electrode delivers a high specific capacity of 500 mAh g(−1) after 500 cycles at a current rate of 0.5 A g(−1) with almost 100% Coulombic efficiency. Furthermore, the weight percentage of SnS(2) in the whole electrode could reach up to 67.2 wt%, much higher than that of common electrode configurations using Cu foil, Al foil, or carbon cloth, significantly highlighting the ultralight characters and advantages of the rGF fabrics for using as binder-free electrodes of SIBs. [Image: see text] ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1007/s40820-019-0297-6) contains supplementary material, which is available to authorized users.