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Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures

[Image: see text] The influence of prepyrolysis temperatures on the spontaneous combustion of wetting coal remains unclear from a macroscopic perspective. To this end, a low-ash and high-volatile wetting coal sample from Western China was pretreated by a programmed heating experimental system at iso...

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Autores principales: Wang, Kai, Fan, Haohao, Gao, Peng, He, Yunzhong, Shu, Pan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7774255/
https://www.ncbi.nlm.nih.gov/pubmed/33403297
http://dx.doi.org/10.1021/acsomega.0c05172
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author Wang, Kai
Fan, Haohao
Gao, Peng
He, Yunzhong
Shu, Pan
author_facet Wang, Kai
Fan, Haohao
Gao, Peng
He, Yunzhong
Shu, Pan
author_sort Wang, Kai
collection PubMed
description [Image: see text] The influence of prepyrolysis temperatures on the spontaneous combustion of wetting coal remains unclear from a macroscopic perspective. To this end, a low-ash and high-volatile wetting coal sample from Western China was pretreated by a programmed heating experimental system at isothermal pyrolysis temperatures of 50, 80, 110, 140, and 170 °C under nitrogen atmosphere and then cooled to room temperature; after that, the oxidation heating experiment was carried out within the range of 30–170 °C. The results indicated that, when the wetting coal samples were subjected to isothermal pyrolysis experiments, the concentrations of CO and CO(2) gradually decreased with the prepyrolysis time, during which the cumulative value of CO increased with the prepyrolysis temperatures, while the change trend of CO(2) is first increased, then decreased, and then increased. In terms of the oxidative heating experiment, the CO concentration of prepyrolyzed coal samples was higher than that of raw coal before 70 °C and then gradually lower than that of the raw coal with the increasing temperature. The CO(2) concentration of coal samples with prepyrolysis temperature of 170 °C is significantly lower than that of other coal samples. According to the characteristic parameters of CO and CO(2) concentrations, oxygen consumption rate, and exothermic intensity, it is inferred that the coal sample with a prepyrolysis temperature of 140 °C exhibited the highest spontaneous combustibility. The experimental results have a certain guiding role for the safe mining of coal seam and the prevention and control on spontaneous combustion.
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spelling pubmed-77742552021-01-04 Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures Wang, Kai Fan, Haohao Gao, Peng He, Yunzhong Shu, Pan ACS Omega [Image: see text] The influence of prepyrolysis temperatures on the spontaneous combustion of wetting coal remains unclear from a macroscopic perspective. To this end, a low-ash and high-volatile wetting coal sample from Western China was pretreated by a programmed heating experimental system at isothermal pyrolysis temperatures of 50, 80, 110, 140, and 170 °C under nitrogen atmosphere and then cooled to room temperature; after that, the oxidation heating experiment was carried out within the range of 30–170 °C. The results indicated that, when the wetting coal samples were subjected to isothermal pyrolysis experiments, the concentrations of CO and CO(2) gradually decreased with the prepyrolysis time, during which the cumulative value of CO increased with the prepyrolysis temperatures, while the change trend of CO(2) is first increased, then decreased, and then increased. In terms of the oxidative heating experiment, the CO concentration of prepyrolyzed coal samples was higher than that of raw coal before 70 °C and then gradually lower than that of the raw coal with the increasing temperature. The CO(2) concentration of coal samples with prepyrolysis temperature of 170 °C is significantly lower than that of other coal samples. According to the characteristic parameters of CO and CO(2) concentrations, oxygen consumption rate, and exothermic intensity, it is inferred that the coal sample with a prepyrolysis temperature of 140 °C exhibited the highest spontaneous combustibility. The experimental results have a certain guiding role for the safe mining of coal seam and the prevention and control on spontaneous combustion. American Chemical Society 2020-12-17 /pmc/articles/PMC7774255/ /pubmed/33403297 http://dx.doi.org/10.1021/acsomega.0c05172 Text en © 2020 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Wang, Kai
Fan, Haohao
Gao, Peng
He, Yunzhong
Shu, Pan
Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title_full Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title_fullStr Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title_full_unstemmed Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title_short Spontaneous Combustion Characteristics of Wetting Coal under Different Prepyrolysis Temperatures
title_sort spontaneous combustion characteristics of wetting coal under different prepyrolysis temperatures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7774255/
https://www.ncbi.nlm.nih.gov/pubmed/33403297
http://dx.doi.org/10.1021/acsomega.0c05172
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