A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents

This study reported a series of cube-shaped polyoxoniobates, {MCu(12)O(8))(Cu(12)X(m)O(n))(Nb(7)(OH)O(21))(8)} [M = Nb(1, 2), Ln(3+)(3), X = I(1, m = 3, n = 3; 2, m = 5, n = 1), Br(3, m = 5, n = 1)]. As the first octahedral Cu(12)X(m)O(n) cluster incorporated polyoxoniobate, the cube-shaped three-sh...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Yan-Lan, Zhang, Rong-Tao, Sun, Yan-Qiong, Li, Xin-Xiong, Zheng, Shou-Tian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7775552/
https://www.ncbi.nlm.nih.gov/pubmed/33392148
http://dx.doi.org/10.3389/fchem.2020.586009
_version_ 1783630493250486272
author Wu, Yan-Lan
Zhang, Rong-Tao
Sun, Yan-Qiong
Li, Xin-Xiong
Zheng, Shou-Tian
author_facet Wu, Yan-Lan
Zhang, Rong-Tao
Sun, Yan-Qiong
Li, Xin-Xiong
Zheng, Shou-Tian
author_sort Wu, Yan-Lan
collection PubMed
description This study reported a series of cube-shaped polyoxoniobates, {MCu(12)O(8))(Cu(12)X(m)O(n))(Nb(7)(OH)O(21))(8)} [M = Nb(1, 2), Ln(3+)(3), X = I(1, m = 3, n = 3; 2, m = 5, n = 1), Br(3, m = 5, n = 1)]. As the first octahedral Cu(12)X(m)O(n) cluster incorporated polyoxoniobate, the cube-shaped three-shell structure of {MCu(12)O(8))(Cu(12)X(m)O(n))(Nb(7)(OH)O(21))(8)} polyanion contains a {MCu(12)O(8)} body-centered cuboctahedron, a {Cu(12)X(m)O(n)} octahedron and a {Cu(12)(Nb(7)(OH)O(21))(8)} cube. Compounds 1, 2, 3 show effective catalytic activities for the hydrolytic decomposition of chemical warefare agent simulants.
format Online
Article
Text
id pubmed-7775552
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher Frontiers Media S.A.
record_format MEDLINE/PubMed
spelling pubmed-77755522021-01-02 A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents Wu, Yan-Lan Zhang, Rong-Tao Sun, Yan-Qiong Li, Xin-Xiong Zheng, Shou-Tian Front Chem Chemistry This study reported a series of cube-shaped polyoxoniobates, {MCu(12)O(8))(Cu(12)X(m)O(n))(Nb(7)(OH)O(21))(8)} [M = Nb(1, 2), Ln(3+)(3), X = I(1, m = 3, n = 3; 2, m = 5, n = 1), Br(3, m = 5, n = 1)]. As the first octahedral Cu(12)X(m)O(n) cluster incorporated polyoxoniobate, the cube-shaped three-shell structure of {MCu(12)O(8))(Cu(12)X(m)O(n))(Nb(7)(OH)O(21))(8)} polyanion contains a {MCu(12)O(8)} body-centered cuboctahedron, a {Cu(12)X(m)O(n)} octahedron and a {Cu(12)(Nb(7)(OH)O(21))(8)} cube. Compounds 1, 2, 3 show effective catalytic activities for the hydrolytic decomposition of chemical warefare agent simulants. Frontiers Media S.A. 2020-12-18 /pmc/articles/PMC7775552/ /pubmed/33392148 http://dx.doi.org/10.3389/fchem.2020.586009 Text en Copyright © 2020 Wu, Zhang, Sun, Li and Zheng. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Wu, Yan-Lan
Zhang, Rong-Tao
Sun, Yan-Qiong
Li, Xin-Xiong
Zheng, Shou-Tian
A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title_full A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title_fullStr A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title_full_unstemmed A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title_short A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu(12)X(m)O(n) Clusters With Hydrolytic Decomposition for Chemical Warfare Agents
title_sort series of cube-shaped polyoxoniobates encapsulating octahedral cu(12)x(m)o(n) clusters with hydrolytic decomposition for chemical warfare agents
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7775552/
https://www.ncbi.nlm.nih.gov/pubmed/33392148
http://dx.doi.org/10.3389/fchem.2020.586009
work_keys_str_mv AT wuyanlan aseriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT zhangrongtao aseriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT sunyanqiong aseriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT lixinxiong aseriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT zhengshoutian aseriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT wuyanlan seriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT zhangrongtao seriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT sunyanqiong seriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT lixinxiong seriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents
AT zhengshoutian seriesofcubeshapedpolyoxoniobatesencapsulatingoctahedralcu12xmonclusterswithhydrolyticdecompositionforchemicalwarfareagents

Ejemplares similares