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Synthesis, structure, and theoretical studies of a calcium complex of a unique dianion derived from 1-methyl­pyrrolidin-2-one

The title compound, catena-poly[[tetra­kis­(1-methyl­pyrrolidin-2-one-κO)calcium(II)]-μ-(E)-1,1′-dimethyl-2,2′-dioxo-1,1′,2,2′-tetra­hydro-[3,3′-bipyrrolyl­idene]-5,5′-bis­(thiol­ato)-κ(2) O:O′], [Ca(C(10)H(8)N(2)O(2)S(2))(C(5)H(9)NO)(4)](n), 1, crystallizes in the triclinic space group P [Image: se...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Purdy, Andrew P., Brown, Paul A., Gunlycke, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784048/
https://www.ncbi.nlm.nih.gov/pubmed/33520286
http://dx.doi.org/10.1107/S205698902001628X