Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations

The crystal structures are reported of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-di­fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K(+)·C(12)H(8)BF(2)O(−), (II), featuring a polymeric...

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Autores principales: Budanow, Alexandra, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784652/
https://www.ncbi.nlm.nih.gov/pubmed/33520264
http://dx.doi.org/10.1107/S2056989020015066
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author Budanow, Alexandra
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Budanow, Alexandra
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Budanow, Alexandra
collection PubMed
description The crystal structures are reported of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-di­fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K(+)·C(12)H(8)BF(2)O(−), (II), featuring a polymeric structure, and bis­(tetra­phenyl­phospho­nium) bis­(6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide) aceto­nitrile tris­olvate, 2C(24)H(20)P(+)·2C(12)H(8)BF(2)O(−)·3CH(3)CN, (III), which is composed of discrete cations, anions and aceto­nitrile solvent mol­ecules linked by C—H⋯O, C—H⋯N and C—H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.
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spelling pubmed-77846522021-01-29 Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations Budanow, Alexandra Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications The crystal structures are reported of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide (or 9,9-di­fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide, K(+)·C(12)H(8)BF(2)O(−), (II), featuring a polymeric structure, and bis­(tetra­phenyl­phospho­nium) bis­(6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide) aceto­nitrile tris­olvate, 2C(24)H(20)P(+)·2C(12)H(8)BF(2)O(−)·3CH(3)CN, (III), which is composed of discrete cations, anions and aceto­nitrile solvent mol­ecules linked by C—H⋯O, C—H⋯N and C—H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures. International Union of Crystallography 2020-11-17 /pmc/articles/PMC7784652/ /pubmed/33520264 http://dx.doi.org/10.1107/S2056989020015066 Text en © Budanow et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Budanow, Alexandra
Lerner, Hans-Wolfram
Bolte, Michael
Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title_full Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title_fullStr Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title_full_unstemmed Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title_short Two salts of the 6,6-di­fluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
title_sort two salts of the 6,6-di­fluoro-6h-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784652/
https://www.ncbi.nlm.nih.gov/pubmed/33520264
http://dx.doi.org/10.1107/S2056989020015066
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