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Crystal structure of the coordination polymer catena-poly[[bis­[hy­droxy(phen­yl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′]

In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis­(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy­droxy(phen­yl)acetate] anions in a slightly distorted octa­hedral coordination geometry. The...

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Detalles Bibliográficos
Autores principales: Fwu Ming, Shen, Shie Fu, Lush
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/
https://www.ncbi.nlm.nih.gov/pubmed/33520271
http://dx.doi.org/10.1107/S2056989020014322
Descripción
Sumario:In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis­(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy­droxy(phen­yl)acetate] anions in a slightly distorted octa­hedral coordination geometry. The 1,2-bis­(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π inter­actions and π–π inter­actions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis­(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis­(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component.