Cargando…
Crystal structure of the coordination polymer catena-poly[[bis[hydroxy(phenyl)acetato-κ(2) O (1),O (2)]zinc(II)]-μ(2)-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]
In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7784659/ https://www.ncbi.nlm.nih.gov/pubmed/33520271 http://dx.doi.org/10.1107/S2056989020014322 |
Sumario: | In the title polymeric Zn(II) compound, [Zn(C(8)H(7)O(3))(2)(C(12)H(12)N(2))](n), the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The 1,2-bis(pyridin-4-yl)ethane unit bridges two Zn(II) cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π interactions and π–π interactions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component. |
---|